Clscc chloride stress corrosion cracking mechanism china. Chloride stress corrosion cracking in austenitic stainless steel. Stress corrosion cracking of insulating jackets often results from airborne salts in coastal regions. Chlorideinduced stress corrosion cracking of 316 stainless. The use of this stainless steel grade in chloride containing environments is not normally.
It can be detrimental to austenitic stainless steels, one of the main reasons these steels are not considered a cureall for corrosion problems. Stresses can occur for a variety of reasons, including welding, physical damage, forming, machining, grinding, heat treatment, and operating stresses. External chloride stress corrosion cracking ecscc of insulated austenitic stainless steels e. Stress corrosion cracking is a failure mechanism that is caused by environment, susceptible material, and tensile stress. Whenever stainless steel is exposed to chloride concentrations and stress levels, chloride stress corrosion cracking cscc can occur. Stainless steels are more resistant to general corrosion compared with carbon steel. Chloride stress corrosion cracks were also found at the corrosion sites. Stress relieved samples were uniaxially prestrained to 5% and were loaded with nine levels of mgcl 2, investigating cl. Chloride stress corrosion cracking scc of type 304 and 304l austenitic stainless steels ss was studied by a constant load method in air at a temperature of 353 k with relative humidity rh of.
Stress corrosion cracking scc stainless steel test specimens were simultaneously subjected to mechanical stress and exposed to 8%wt. Tp304 ss and tp316 ss can occur when water containing chloride is present underneath insulation, external metal skin temperature exceeds approximately 50 c, and there is no surface protection or when the protective coating e. The mechanism of chloride stress corrosion cracking clscc is complex and the current understanding is discussed in section 5 of this report. Scc is a form of corrosion that occurs in nearly all alloys, including the grades of stainless steel commonly used in brewery equipment types 304, 304l, 316, and 316l. Introduction one of the most accepted mechanisms of stress corrosion cracking scc i. A precursor of stress corrosion cracking in chloridebearing environments is pitting corrosion, occurring if the stainless steel is not sufficiently resistant to pitting. It occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride ions and high temperature. Chloride stress corrosion cracking clscc is one the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical. With regard to the safe temperature for carbon steel, the reader should look at the curve in figure 1. Stress corrosion cracking scc 1 is a common and dangerous form of cracking that occurs due to the combination of stress and corrosive environments. Therefore, the scc concerns for spent fuel storage canisters identified in a november 2004 presentation by nuclear and. Susceptibility to stress corrosion cracking of 254smo ss. Protective coating for stainless steel thurmalox 70.
Chloride stress corrosion is a type of intergranular corrosion and occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride ions. Stress corrosion cracking international institute of. The most common environmental exposure condition responsible for scc of stainless steels is the presence of chlorides. For example, chloride stress corrosion cracking of austenitic stainless steel has been experienced in hotwater jacketed pipes carrying molten chocolate in the food industry. Monitoring of chloride stress corrosion cracking of austenitic stainless steel. The most common type of stress corrosion cracking in stainless steels occurs in chloride environments, which will be the focus of this discussion. Chloride stress corrosion cracking and 316 stainless steel moltenmetal chemical 20 jul 11 07. How to reduce the risk of stress corrosion cracking scc the risk of stress corrosion cracking scc. There are, consequently, a number of approaches that we can use to prevent scc, or at least to give an acceptable lifetime. Most people have seen the spiderwebbed and lightening array type network of highly branched cracks that is common with chloride cracking of sss.
Stress corrosion cracking of sensitized type 304 stainless. It occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride. Chloride induced stress corrosion cracking of stainless. The most common type of stress corrosion cracking in stainless steels occurs in chloride. Chloride oxygen stress corrosion cracking mechanisms of austenitic chromiumnickel steels in high purity water at 250 to 350 c over a wide range of stress levels is reported. Chloride stress corrosion cracking clscc is one the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries. An investigation was carried out on the effect of stress, chloride concentration, temperature and oxygen on the stress corrosion cracking behaviour of 188 and 18 mo steels. Stress corrosion cracking is the cracking of a susceptible metal under the mixed. Prevention of external chloride stress corrosion cracking of. The main drawbacks of stainless steels is that these alloys are sensitive to chloride induced localized attack like pitting and crevice attack and stress corrosion cracking. The influence of salt concentration, ph values and the addition of thiosulfate was examined. The chloride induced stress corrosion cracking scc resistance of nitrogenalloyed, powder metallurgically pm produced and hot isostatically pressed hip duplex stainless.
The chloride induced stress corrosion cracking scc resistance of nitrogenalloyed, powder metallurgically pm produced and hot isostatically pressed hip duplex stainless steels dss was investigated and compared to the scc resistance of two commercial wrought forged dss. Intergranular stress corrosion cracking caused failure of two type304 stainless steel outlet nozzles in highpurity heavywater moderator service in nuclear reactors. Chloride stress corrosion cracking inspectioneering. The hsl research report 902 reference 1 covers the susceptibility of stainless. Chloride induced stress corrosion cracking of stainless steel. This paper described the mechanism of chloride induced stress corrosion cracking of oil tube as a result of improper material selection and lack of maintenance. In all cases of failure by stress corrosion cracking, the following three factors must be present. Chlorideinduced stress corrosion cracking of powder. Jan 22, 20 stress corrosion cracking is a failure mechanism that is caused by environment, susceptible material, and tensile stress. Chloride stress corrosion cracking methods of minimizing.
Monitoring of chloride stress corrosion cracking of austenitic. Failure analysis of corrosion on stainless steel fasteners. The incubation time for stress corrosion cracking can be very short, sometimes measured in hours. Modes such as pitting, crevice, stress corrosion cracking, sulfide stress corrosion cracking, integranular, galvanic, contact, passivation and pickling are covered. Oct 08, 20 if the atmosphere contains halides this can leave any stainless steel susceptible to chloride stress corrosion cracking ciscc. Chloride stress corrosion cracking in austenitic stainless. Scc is often associated with chlorides, but can also occur with caustics and other corrosive media.
The use of a duplex stainless steel with molybdenum such as stainless alloys 2205 or 2507 would resist crevice corrosion and stress corrosion cracking. Stress corrosion cracking scc is a common issue with many specialty alloys. When stainless steels are fully immersed, it is rare to see chloride stress corrosion cracking. Or a structure under static tensile stress, much below the yield stress. Table 6 lists the relative corrosion resistance of the aisi standard numbered stainless steels in seven broad categories of. Thurmalox 70 is an air drying, silicone based heat resistant coating that protects thermally insulated austenitic stainless steel from chloride induced stress corrosion cracking. As its name suggests, scc takes the form of a network of cracks that eventually will lead to sudden, catastrophic failure in your tanks. This article describes the susceptibility of 316l stainless steel to stress corrosion cracking scc in a nitritecontaining chloride.
It is thought to start with chromium carbide deposits along grain boundaries that leave the metal open to corrosion. Chloride stress corrosion cracking cscc is a type of intergranular corrosion. Chloride stress corrosion cracking stainless steel the three conditions that must be present for chloride stress corrosion to occur are as follows. It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially. Effects of marine environments on stress corrosion cracking. These alloys for example hastelloy c276 are the extremely resistant materials to the chloride induced localized attack that limits the application of austenitic stainless. Jan 08, 2002 while stainless steels are often used for their corrosion resistance, they do in fact suffer from corrosion under certain circumstances. Although no stainless steel grade is totally immune. Deterioration by clscc can lead to failures that have the potential to release stored energy andor hazardous substances. Essentially clscc involves a combination of the electrochemistry of metal dissolving over a highly localised area, i. Pdf stress corrosion cracking of austenitic stainless. Drop evaporation test method, author steinsmo, u and drugli, j m, abstractnote stress corrosion cracking scc of chloride exposed stainless steels under evaporative conditions has for long been recognized as a factor that needed special attention. Chloride stress corrosion is a type of intergranular corrosion and occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride ions, and high temperature.
How to reduce the risk of stress corrosion cracking scc the risk of stress corrosion cracking scc can be minimized through plant and equipment design. Chloride stress corrosion cracking of aisi 316 stainless steel downhole pressure memory gauge cover. Stress corrosion cracking facts and how to reduce the. Tp304 ss and tp316 ss can occur when water containing chloride is present underneath insulation, external.
If the atmosphere contains halides this can leave any stainless steel susceptible to chloride stress corrosion cracking ciscc. Chloride ions are present in the environment dissolved oxygen is present in the environment metal is under tensile stress austenitic stainless. The use of 316l would be more resistant to crevice corrosion attack. Chloride stress corrosion cracking and 316 stainless steel. The hsl research report 902 reference 1 covers the susceptibility of stainless steel to ciscc in some detail and links to other research papers and published documents. A precursor of stress corrosion cracking in chloride bearing environments is pitting corrosion, occurring if the stainless steel is not sufficiently resistant to pitting. Stress corrosion cracking of an austenitic stainless steel in. Therefore, duplex stainless steels are often preferred over austenitic stainless steels in applications where chloride scc is a problem. Integral to johns manville thermo1200 and to sproule wr1200 is xox corrosion inhibitor, a distinctive formula and process that inhibits corrosion to the outside surfaces of pipe and equipment, especially stress corrosion cracking. Stress corrosion cracking of an austenitic stainless steel. Pdf chloride induced stress corrosion cracking of type 304. Introduction stress corrosion cracking scc of austenitic 304 stainless steel in chloride environment is a common problem in industries. Chloride stress corrosion cracking in austenitic stainless steel chloride stress corrosion cracking clscc is one of the most common reasons why austenitic stainless steel pipework and vessels.
Effects of marine environments on stress corrosion. Temperature is a significant environmental factor affecting cracking. When stainless steels are fully immersed, it is rare to see chloride stress corrosion cracking at temperatures below 60 c 150 f. Stress corrosion cracking in a brewery paul mueller company. Chloride stress corrosion cracking clscc is a type of stress corrosion cracking scc and is one of the most well known forms of scc in the refining and chemical processing industries. The effect of salt loading on chlorideinduced stress. Ammonium hydroxide stainless steela ahow good resistance to all concentrations of ammonia. While no stainless steel can be completely immune, swageloks alloy 316 stainless steel fittings have performed exceptionally well in testing. Overstressed ubends of types 304 and 347 stainless steels were exposed to water containing chloride ions to determine the susceptibility of these steels to stress corrosion cracking between the temperatures of 165 f and 200 f. The failure cracks propagated from intergranular pickling damage to the 12inchthick steel, which was sensitized during initial fabrication. The effect of salt loading on chlorideinduced stress corrosion cracking in 304 l was studied at atmospheric pressure. Or a structure under static tensile stress, much below the yield stress, in contact with corrosive environment may fail due to scc. The combination of tensile stress and a specific corrosive environment can crack stainless steels. The probability of failure and the speed of crack propagation are governed by the temperature of the stainless steel and the chloride.
It is difficult to control the temperature, while changing pipe material or eliminating residual stresses associated with welding and forming the pipework is costly and. Chloride scc is clearly the bane of austenitic stainless steels and one of the main reasons they are not the miracle cure for many corrosion problems. This limits the usefulness of austenitic stainless steel for containing water with higher than a few ppm content of chlorides at temperatures above 50 c. This mode of attack is termed stress corrosion cracking scc. It can be detrimental to austenitic stainless steels, one of the main reasons these steels are not considered a cureall for corrosion. Yes the nace mr 0175 iso 15156 addresses only hydrogen sulfide stress corrosion cracking also called hydrogen stress cracking,and a dozen other names.
The observed crack propaga tion is the result of the combined and synergistic interaction of mechanical stress and corrosion re actions. Assessment of susceptibility to chloride stress corrosion. Chloride stress corrosion involves selective attack of a metal along its grain boundaries. Chloride stress corrosion cracking of austenitic stainless. Oct 21, 2019 chloride stress corrosion cracking cscc is a type of intergranular corrosion. Most people have seen the spiderwebbed and lightening array type network of highly branched cracks that is common with chloride cracking. The susceptibility to stress corrosion cracking scc of solubilized and sensitized 254smo ss was studied in sodium chloride, and sodium fluoride solutions at 80 c and sulfuric acid solutions in presence of sodium chloride at 25 c. Stress corrosion cracking the international institute of. Stress corrosion cracking scc is the growth of crack formation in a corrosive environment. Stresscorrosion cracking scc is a term used to describe service failures in engineering materials that occur by slow, environmentally induced crack propagation. The environmental factors that increase the cracking susceptibility include higher temperatures, increased chloride content, lower ph, and higher levels of tensile stress.
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